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Calcium Fumarate Trihydrate Anhydrous SDS Safety Data Sheet of Supplier Exporter Manufacturers' Representative

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Calcium Fumarate Trihydrate Anhydrous
CAS Number: Anhydrous 19855-56-2 or Trihydrate 28376-12-7

Molecular Formula: CaC4H2O4 for Anhydrous
Molecular Weight: 154.2
E number: E367

Calcium Fumarate Suppliers
Calcium Fumarate Trihydrate Anhydrous

Calcium Fumarate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
02-Dec-24

1. Product Identification

Product Name & Other Names: Calcium Fumarate.
CAS No.: Anhydrous 19855-56-2 or Trihydrate 28376-12-7
EINECS EC Code number: 2243-376-3
Intended use: Laboratory Chemicals and Industrial Manufacturing Use.
Supplier: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
NONE

Signal Word: None

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P281: Use personal protective equipment as required.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

3. Composition/Information on Ingredients

Product Name & Other Names: Calcium Fumarate.
CAS No.: 19855-56-2
EINECS EC Code number: 2243-376-3
Percent: 99 - 100%

4. First Aid Measures

Inhalation: Remove to fresh air. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used. Cover the irritated skin with an emollient. If irritation persists, seek medical attention.
Eye Contact: Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek medical attention.

5. Fire Fighting Measures

Fire: Calcium Fumarate is not considered to be a fire hazard.
Fire Extinguishing Media: In case of fire, use carbon dioxide, dry chemical powder or appropriate foam. Avoid solid water jet as it can scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Water mist may be used to keep containers cool.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Maintain eye wash fountain and quick-drench facilities in work area. Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice.

9. Physical and Chemical Properties

Appearance: Calcium Fumarate is white, granules or crystalline powder.
Odor: Odorless.
Odor threshold: Not applicable.
pH: No information found.
Relative density: No information found.
Melting point/freezing point: No information found.
Boiling Point: Decomposes.
Flash point: No information found.
Auto-ignition temperature: No information found.
Decomposition temperature: No information found.
Upper/lower flammability or explosive limits: No information found.
Vapor pressure: No information found.
Vapor density: No information found.
Evaporation rate: No information found.
Flammability (solid, gas): No information found.
Partition coefficient: n-octanol/water: No information found.
Solubility(ies): No information found.
Viscosity: No information found.

10. Stability and Reactivity

Stability: Calcium Fumarate is stable under ordinary storage conditions.
Hazardous Decomposition Products: At higher temperatures, substance decomposes into Calcium oxide, Carbon dioxide and Carbon monoxide and fumes.
Hazardous Polymerization: This substance does not polymerize.
Incompatibilities: Strong oxidizing agents.

11. Toxicological Information

Oral LD50 Rat: No information found.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: No information found.
Mutagenic Effects: No information found.
Developmental Toxicity: No information found.
Reproductive Effects: No information found.

12. Ecological Information

Toxicity to fish: No information found.
Persistence and Degradability: No information found.
Mobility: No information found.
Bioaccumulation/ Accumulation: No information found.
Results of PBT and vPvB assessment: No information found for assessment.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Follow all the pollution control rules.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe: Not regulated.
IMDG/IMO: Not regulated.
IATA/ICAO: Not regulated.

15. Regulatory Information

USA:
California Proposition 65: Not listed for birth defects, reproductive harm and cancer.
SARA 311/312 Hazards: None applicable.

16. Other Information

DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable.This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.


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16 April, 2025