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Diethanolamine or 2,2'-Iminodiethanol or DEA SDS Safety Data Sheet of Supplier Exporter Manufacturers' Representative |
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Diethanolamine or 2,2'-Iminodiethanol or DEA
CAS Number: 111-42-2
Molecular Formula: C4H11NO2 or HN(CH2CH2OH)2
Molecular Weight: 105.14
Diethanolamine or 2,2'-Iminodiethanol or DEA
Diethanolamine or 2,2'-Iminodiethanol SDS GHS, Material Safety Data Sheet
MSDS GHS, Material Safety Data Sheet 04-Feb-24
1. Product Identification
Product Name & Other Names: Diethanolamine or 2,2'-Iminodiethanol
CAS No.: 111-42-2
EINECS EC No.: 203-868-0
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: American Molecules, 9910 Bent Oak Dr, Houston, TX 77040, USA.
Call Toll Free: 1-855-55-AMMOL 1-855-552-6665.
In case of emergency contact: Will be given with the supply.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP):
Acute toxicity, Oral (Category 4) H302
Skin irritation (Category 2), H315
Serious eye damage (Category 1), H318
Specific target organ toxicity - repeated exposure (Category 2), H373
Long-term (chronic) aquatic hazard (Category 3), H412
Labeling according to Regulation (EC) No 1272/2008
GHS Label Elements Corrosive |
GHS Label Elements |
Signal Words: Danger
Hazard statements:
H302: Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H373 May cause damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P233: Keep container tightly closed.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P301 + P312 + P330: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
3. Composition/Information on Ingredients
Product Name & Other Names: Diethanolamine or 2,2'-Iminodiethanol
CAS No.: 111-42-2
EINECS EC No.: 203-868-0
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
5. Fire Fighting Measures
Flash Point: 138C
Auto-ignition Temperature: 662C
Products of Combustion: Carbon oxides, Nitrogen oxides (NOx) and fumes.
Fire Extinguishing Media: Use water spray or fog, alcohol-resistant foam, dry chemical, or carbon dioxide. Cool containing vessels with water jet to prevent pressure build-up, auto-ignition, or explosion. Do not allow run-off from firefighting to enter drains or water courses.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.
6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Remove all sources of ignition. Provide proper ventilation. If solid/powder - carefully sweep up the material without causing dust. Dispose of in accordance with local regulations.
7. Handling and Storage
Precautions for safe handling: Keep away from sources of ignition - No smoking. Take measures to prevent the build-up of electrostatic charge. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like Oxidizing agents, Acids, Copper, Zinc, Iron. Keep the product in its original container well sealed, in a dry and ventilated area, away from potential sources of ignition and protected from light. Protect against physical damage. Air sensitive. Handle and store under inert gas.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
ACGIH TLV TWA: 1 mg/m3 Skin.
OSHA PEL (Vacated) TWA: 3 ppm; (Vacated) TWA: 15 mg/m3
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: Clear colorless liquid.
Odor: Ammonia-like odor.
Odor threshold: Not available.
pH: around 11 to 12
Relative Density: 1.1
Boiling Point: 217C
Melting Point: 28C
Flash Point: 138C
Auto-ignition Temperature: about 375C literature.
Decomposition temperature: No data found.
Upper/lower flammability or explosive limits: No data found.
Vapor Pressure (mm Hg): No data found.
Vapor Density (Air=1): No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility: Soluble in water.
Viscosity: No data found.
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage. Vapor/air-mixtures are explosive at intense warming. The product is air sensitive and Hygroscopic.
Hazardous Decomposition Products: It emits Carbon oxides, Nitrogen oxides (NOx) and fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Oxidizing agents, Acids, Copper, Zinc, Iron.
Conditions to Avoid: Incompatibles, Air, Moisture, Heat, flames, and sparks & light.
11. Toxicological Information
Toxicity data
LD50 Oral - Rat - male and female - 1600 mg/kg.
LD50 Dermal - Rabbit - male - 8328 mg/kg.
Carcinogenicity: IARC 2B - Group 2B: Possibly carcinogenic to humans (Diethanolamine).
Epidemiology: No data found.
Teratogenicity: No data found.
Reproductive Effects: No data found.
Mutagenicity: No data found.
Neurotoxicity: No data found.
12. Ecological Information
Environmental Toxicity: Harmful to aquatic life with long lasting effects.
Toxicity to fish: static test LC50 - Pimephales promelas (fathead minnow) - 1.460
mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: static test EC50 - Ceriodaphnia dubia (water flea) - 30,1 mg/l - 48 h.
Persistence and Degradability: Persistence is unlikely due to its water solubility.
Mobility: Will likely be mobile in the environment due to its water solubility.
Bioaccumulation/ Accumulation: No data found.
Results of PBT and vPvB assessment: No data found.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.
14. Transport Information
Land Transport DOT USA, TDG Canada & ADR/RID Europe: Not regulated.
Sea Transport IMDG/IMO: Not regulated.
Air Transport IATA/ICAO: Not regulated.
15. Regulatory Information
USA:
SARA 311/312 Hazards: See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
16. Other Information
European Labeling in Accordance with EC Directives:
H302: Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H373 May cause damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.
Please visit Main Page of Diethanolamine or 2,2'-Iminodiethanol or DEA Suppliers.
American Molecules, also known as ammol.org is a distributor, supplier and manufacturers' representative of all types of Pharmaceuticals, Functional Ingredients, Excipients and Specialty Chemicals in Texas USA. Our principals manufacture supply and export USP NF BP, Ph Eur, etc grades of chemicals pure and reagent grade, mineral fortifiers, FCC food grade. Tailor made particle size and customized specifications are offered. The principal's facility is having one or more of the certifications like FDA approval and GLP, cGMP, ISO9001, ISO14001, ISO/IEC 17025, ISO22000, FSSC 22000, ISO45001, FSSAI, Kosher, HALAL, COPP, WHO-GMP certified and Written Confirmation (WC) for export to Europe is available. The manufacturers suppliers and exporters observe WHO Good Manufacturing Practices and Good Laboratory Practices.
Suppliers and Manufacturers' Representative:
9910 Bent Oak Dr
Houston, TX 77040, USA
Call Toll Free: 1-855-55-AMMOL 1-855-552-6665
Email: info@ammol.org