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Itaconic Acid or Methylidenesuccinic Acid or 2-Methylidenebutanedioic Acid SDS Safety Data Sheet of Supplier Exporter Manufacturers' Representative |
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Itaconic Acid or Methylidenesuccinic Acid or 2-Methylidenebutanedioic Acid
CAS Number: 97-65-4
Molecular Formula: C5H6O4 or HO2CCH2C(=CH2)CO2H
Molecular Weight: 130.10
Itaconic Acid or Methylidenesuccinic Acid or 2-Methylidenebutanedioic Acid
Itaconic acid or methylidenesuccinic acid or 2-Methylidenebutanedioic acid SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 06-Dec-24
SECTION 1. PRODUCT IDENTIFICATION
Product Name & Other Names: Itaconic acid or methylidenesuccinic acid or 2-Methylidenebutanedioic acid.
CAS Number: 97-65-4
EINECS EC Number: 202-599-6
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: As per the letterhead.
SECTION 2. HAZARDS IDENTIFICATION
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Serious eye damage (Category 1)
Labeling according GHS USA & Regulation (EC) No 1272/2008
GHS Label Elements Corrosive |
Signal Words: Danger
Hazard statements:
H318: Causes serious eye damage.
Precautionary statements:
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
SECTION 3. COMPOSITION / INFORMATION ON INGREDIENTS
Product Name & Other Names: Itaconic acid or methylidenesuccinic acid or 2-Methylidenebutanedioic acid.
CAS Number: 97-65-4
EINECS EC Number: 202-599-6
SECTION 4. FIRST AID MEASURES
Always seek medical attention after first aid measures are provided.
Eye Contact: Do not allow victim to rub eye (s). Let the eye (s) water naturally for a few minutes. If particle/dust does not dislodge, flush with lukewarm, gently flowing water for 5 minutes or until particle/dust is removed, while holding eyelid (s) open. If irritation persists, obtain medical attention. DO NOT attempt to manually remove anything stuck to the eye.
Skin Contact: Remove contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Quickly and gently blot or brush away excess chemical. Wash gently and thoroughly with lukewarm gently flowing water and non-abrasive soap for 5 minutes. If irritation persists, repeat flushing. Obtain medical advice.
Inhalation: If symptoms are experienced, remove source of contamination or move victim to fresh air. Obtain medical advice.
Ingestion: Never give anything by mouth if victim is rapidly losing consciousness or is unconscious or convulsing. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING.
SECTION 5. FIRE FIGHTING MEASURES
Fire and Explosion Hazards: Not considered flammable but may burn at high temperatures.
Extinguishing Media: Use means of extinction appropriate for the surrounding fire conditions such as water spray, carbon dioxide, dry chemical, or foam.
Fire Fighting: Apart from oxides of carbon. toxic fumes may result from combustion. As with any fire, fire fighters should be fully trained and wear full protective clothing including an approved, self-contained breathing apparatus which supplies a positive air pressure within a full-face piece mask. Use water spray to cool unopened containers.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Close-fitting safety goggles may be necessary in some circumstances to prevent eye contact.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Contain spill, isolate hazard area, and deny entry. Sweep up or vacuum. Place contaminated material in suitable, labeled containers for final disposal.
SECTION 7. HANDLING AND STORAGE
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing agents, water. Keep away from sources of ignition. Take measures to prevent the build-up of electrostatic charge.Use care during processing to minimize generation of dust. Good housekeeping is important to prevent accumulations of dust. Store below 30C.
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure limits: Contains no substances with occupational exposure limit values in some countries. Better go by 5 mg/m3 TLV ACGIH.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: White powder or crystals.
Odor: None
Odor threshold: Not applicable.
pH: 2 in10 g/l water solution @ 20C
Relative density: 1.6
Freezing/Melting Point/Range: 163C to 169C literature.
Boiling Point: 268C literature.
Flash point: No information found.
Auto-ignition temperature: No information found.
Decomposition temperature: No information found.
Upper/lower flammability or explosive limits: No information found.
Vapor pressure: No information found.
Vapor density: No information found.
Evaporation rate: No information found.
Flammability (solid, gas): No information found.
Partition coefficient: n-octanol/water: No information found.
Solubility: Soluble in water and ethanol, methanol, acetone. Hygroscopic.
Viscosity: No information found.
SECTION 10. STABILITY AND REACTIVITY
Stability and Reactivity: Stable and not considered reactive under normal temperatures and pressures. Hazardous polymerization or runaway reactions will not occur.
Incompatibilities: Oxidizing agents. Avoid excessive heat, spark, flame, ignition dust formation and electrical charging. Also avoid moisture, strong reducing agents, and bases.
Hazardous Decomposition Products: High temperature will generate carbon oxide and fumes.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Toxicity:
LD50 Oral – Rat: >2000 mg/kg
Carcinogenicity: IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity: No information found.
Teratogenicity: No information found.
Mutagenicity: No information found.
SECTION 12. ECOLOGICAL INFORMATION
Eco toxicological data:
Toxicity to fish: LC50 - Oncorhynchus mykiss (rainbow trout) - 190 mg/l - 24 h.
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 240 mg/l - 24 h.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Mobility in soil: No information found.
SECTION 13. DISPOSAL CONSIDERATIONS
Do not wash the material down drain. Put uncontaminated material back into the process if possible. Follow all the pollution control rules.
SECTION 14. TRANSPORT INFORMATION
DOT USA, TDG Canada & ADR/RID Europe: Not controlled.
IATA: Not controlled.
IMDG: Not controlled.
SECTION 15. REGULATORY INFORMATION
USA Regulations:
SARA 311/312 Hazards: See section 2.
California Prop. 65 Components: Not listed.
SECTION 16 - ADDITIONAL INFORMATION
Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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