 |
N-Methyl Piperazine or N-Methylpiperazine or 1-Methylpiperazine SDS Safety Data Sheet of Supplier Exporter Manufacturers' Representative |
Email: info@ammol.org |
Call Toll Free +1-855-552-6665 |
N-Methyl Piperazine or N-Methylpiperazineor or 1-Methylpiperazine
CAS Number: 109-01-3
Molecular Formula: C5H12N2
Molecular Weight: 100.16
N-Methyl Piperazine or N-Methylpiperazine or 1-Methylpiperazine
N-methylpiperazine or N-Methyl Piperazine SDS GHS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 04-Feb-24
1. Product Identification
Product Name & Other Names: N-methylpiperazine or N-Methyl Piperazine.
CAS No.: 109-01-3
EINECS EC No.: 203-639-5
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: American Molecules, 9910 Bent Oak Dr, Houston, TX 77040, USA.
Call Toll Free: 1-855-55-AMMOL 1-855-552-6665.
In case of emergency contact: Will be given with the supply.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP):
Flammable liquids (Category 3) H226
Acute toxicity, Oral (Category 4) H302
Acute toxicity, Dermal (Category 4), H312
Skin corrosion (Category 1C), H314
Acute toxicity, Inhalation (Category 3) H331
Labeling according to Regulation (EC) No 1272/2008
GHS Label Elements Corrosive |
GHS Label Elements |
GHS Label Elements |
Signal Words: Danger
Hazard statements:
H226: Flammable liquid and vapor.
H302 + H312: Harmful if swallowed or in contact with skin.
H314: Causes severe skin burns and eye damage.
H331: Toxic if inhaled.
Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P309 + P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.
P370+378: In case of fire: Use Water spray, Carbon dioxide (CO2), Foam, Dry powder and Sand for extinction.
3. Composition/Information on Ingredients
Product Name & Other Names: N-methylpiperazine or N-Methyl Piperazine.
CAS No.: 109-01-3
EINECS EC No.: 203-639-5
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to physicians: Product is a corrosive material. Use of gastric lavage or emesis is contra-indicated. Possible perforation of stomach or esophagus should be investigated. Do not give chemical antidotes. Asphyxia from glottal oedema may occur. Marked decrease in blood pressure may occur with frothy sputum, and high pulse pressure.
5. Fire Fighting Measures
Products of Combustion: Carbon dioxide, Carbon monoxide, Nitrogen oxides, fumes.
Fire: Inflammable.
Explosion: Explosive in presence of heat.
Fire Extinguishing Media: Use Water spray, Carbon dioxide (CO2), Foam, Dry powder and Sand for extinction. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray or fog is preferred, if water not available use dry chemical, CO2 or regular foam. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Never direct a water jet in the container in order to prevent any splashing of the product which could cause spreading of the fire. Cool containing vessels with water jet in order to prevent pressure build-up, auto-ignition or explosion.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.
6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up and remove to an approved disposal container. Remove all sources of ignition. Provide proper ventilation.
7. Handling and Storage
Precautions for safe handling: No naked lights. No smoking. Use only under a chemical fume hood. Wear personal protective equipment. Use spark-proof tools and explosion-proof equipment. Keep away from open flames, hot surfaces and sources of ignition. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Keep away from sources of ignition - No smoking. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc).
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Keep under nitrogen. Flammables area. Corrosives area. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like acids, acid chlorides, acid anhydrides, strong oxidizing agents.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: Not Established. Keep it below 0.2 ppm. Provide adequate ventilation.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: Clear colorless liquid.
Odor: Amine like.
Odor threshold: Not available.
pH: 11 - 12
Relative density: 0.9.
Melting point/freezing point: -6C.
Initial boiling point and boiling range: 138C.
Flash point: 39C.
Auto-ignition temperature: No data found.
Decomposition temperature: No data found.
Upper/lower flammability or explosive limits: No data found.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility(ies): No data found.
Viscosity: No data found.
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage. Vapour/air-mixtures are explosive at intense warming. Flammable liquid and vapor. May form flammable vapor-air mixture..
Hazardous Decomposition Products: It emits Carbon dioxide, Carbon monoxide, Nitrogen oxides & Toxic Fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Acids, Acid chlorides, Acid anhydrides, Strong oxidizing agents.
Conditions to Avoid: Incompatibles, moisture, air, heat, flame, sparks & light.
11. Toxicological Information
LD50 Oral - Rat - 2.553 mg/kg.
LC50 Inhalation - Mouse - 2 h - 2,7 mg/l.
Carcinogenicity: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Teratogenicity: No data found.
Reproductive Effects: No data found.
Mutagenicity: No data found.
12. Ecological Information
Toxicity to fish: No data found.
Persistence and Degradability: Soluble in water Persistence is unlikely.
Bioaccumulation/ Accumulation: No information available.
Mobility: Will likely be mobile in the environment due to its water solubility.
Results of PBT and vPvB assessment: No data found.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.
14. Transport Information
Land Transport DOT USA, TDG Canada & ADR/RID Europe:
UN Number: UN2734
Shipping Name: Amines, liquid, corrosive, flammable, n.o.s. (1-Methylpiperazine)
Hazard Class: 8 (3); Packing Group: II.
Sea Transport IMDG/IMO:
UN Number: UN2734
Shipping Name: Amines, liquid, corrosive, flammable, n.o.s. (1-Methylpiperazine)
Hazard Class: 8 (3); Packing Group: II.
Air Transport ICAO/IATA:
UN Number: UN2734
Shipping Name: Amines, liquid, corrosive, flammable, n.o.s. (1-Methylpiperazine)
Hazard Class: 8 (3); Packing Group: II.
15. Regulatory Information
USA:
SARA 311/312 Hazards: See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
16. Other Information
European Labeling in Accordance with EC Directives:
H226: Flammable liquid and vapor.
H302 + H312: Harmful if swallowed or in contact with skin.
H314: Causes severe skin burns and eye damage.
H331: Toxic if inhaled.
DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.
Please visit Main Page of N-Methyl Piperazine or N-Methylpiperazine or 1-Methylpiperazine Suppliers.
American Molecules, also known as ammol.org is a distributor, supplier and manufacturers' representative of all types of Pharmaceuticals, Functional Ingredients, Excipients and Specialty Chemicals in Texas USA. Our principals manufacture supply and export USP NF BP, Ph Eur, etc grades of chemicals pure and reagent grade, mineral fortifiers, FCC food grade. Tailor made particle size and customized specifications are offered. The principal's facility is having one or more of the certifications like FDA approval and GLP, cGMP, ISO9001, ISO14001, ISO/IEC 17025, ISO22000, FSSC 22000, ISO45001, FSSAI, Kosher, HALAL, COPP, WHO-GMP certified and Written Confirmation (WC) for export to Europe is available. The manufacturers suppliers and exporters observe WHO Good Manufacturing Practices and Good Laboratory Practices.
Suppliers and Manufacturers' Representative:
9910 Bent Oak Dr
Houston, TX 77040, USA
Call Toll Free: 1-855-55-AMMOL 1-855-552-6665
Email: info@ammol.org