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Potassium monopersulfate or Potassium peroxymonosulfate triple salt SDS Safety Data Sheet of Supplier Exporter Manufacturers' Representative

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Potassium monopersulfate or Potassium peroxymonosulfate triple salt
CAS Number: 70693-62-8

Molecular Formula: 2KHSO5.KHSO4.K2SO4
Molecular Weight: 614.76

Potassium monopersulfate or Potassium peroxymonosulfate triple salt Suppliers
Potassium monopersulfate or Potassium peroxymonosulfate triple salt

Potassium Monopersulfate or Potassium Monopersulphate (or peroxymonopersulfate) Triple Salt SDS, Safety Data Sheet.
MSDS Sheet, Material Safety Data Sheet
 04-Feb-24

1. Product Identification

Product Name/Synonyms: Potassium peroxymonosulfate triple salt or Potassium monopersulfate triple salt Potassium monopersulphate triple salt.
CAS Number: 70693-62-8
EINECS EC Number: 274-778-7
Recommended usage: Industrial Manufacturing.
Supplier: American Molecules, 9910 Bent Oak Dr, Houston, TX 77040, USA.
Call Toll Free: 1-855-55-AMMOL 1-855-552-6665.
In case of emergency contact: Will be given with the supply.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral Category 4 - H302
Skin corrosion/irritation Category 1A, B, C - H314
Specific target organ toxicity (single exposure) Target Organs - Respiratory system Category 3 - H335

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Corrosive
Corrosive

Signal Words: Danger

Hazard statements:
H272: May intensify fire; oxidizer.
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H335: May cause respiratory irritation.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P220: Keep/Store away from clothing/…/combustible materials.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

3. Composition/Information on Ingredients

Ingredient name

%

CAS number

Pentapotassium bis(peroxymonosulphate) bis(sulphate)

≥90

70693-62-8

potassium hydrogensulphate

≤5

7646-93-7

Dipotassium peroxodisulphate

≤5

7727-21-1

Dipotassium disulphate

≤5

7790-62-7

4. First Aid Measures

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used. Wash clothing & shoes before reuse. Get medical attention.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.

5. Fire Fighting Measures

Fire: It is not combustible, but substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition. Heating which may intensify combustion in an existing fire.
Explosion: An explosion hazard when mixed with finely powdered organic matter, metal powder, or reducing agents. Avoid grinding or intense mixing.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire Water can be used.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.

6. Accidental Release Measures

Personal precautions, protective equipment, environmental precautions, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Keep away from drains, surface and groundwater and soil.
Methods and materials used for containment Cleanup procedures and Storage: It is an oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep damp using water spray. Do not touch spilled material. Prevent entry into sewers. Eliminate all ignition sources. Do not touch or walk through spilled material.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices with proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like reducing agents, organic material, sodium peroxide, water, and powdered metals, especially aluminum. Moisture must be avoided. Avoid storage on wood floors.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
TWA: 5 (mg/m3) from OSHA (PEL) [United States] Inhalation Respirable.
USA ACGIH TLV: TWA: 0.1 mg/m3.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice.

9. Physical and Chemical Properties

Appearance: Potassium peroxymonosulfate or Potassium Monosulfate is white crystals.
Odor: Odorless.
Odor threshold: Not applicable.
pH: 2.3 at 10g/1000 ml water @ 20C
Relative density: 1.98
Melting point/freezing point: 120C (248F) Decomposes.
Initial boiling point and boiling range: No data found.
Flash point: No data found.
Auto-ignition temperature: No data found.
Decomposition temperature: No data found.
Upper/lower flammability or explosive limits: No data found.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility: 256 g/l000 ml water @ 20C
Viscosity: Not data found.

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage. Stability decreases in the presence of moisture.
Hazardous Decomposition Products: Decomposed by moisture to form oxygen and ozone.
Hazardous Polymerization: Will not occur.
Incompatibilities: Reducing agents, organic material, sodium peroxide, water and powdered metals especially aluminum. Heat and Strong bases & Acids must be avoided.
Conditions to Avoid: Moisture, combustible materials, and incompatibles.

11. Toxicological Information

Product/ingredient name

Dose

Test

Potassium monopersulphate, LD50 Oral, Rat - Male, Female

500 mg/kg

OECD 423 Acute Oral toxicity – Acute Toxic Class Method

Potassium monopersulphate, LD50 Dermal, Rat - Male, Female

>5000 mg/kg Extrapolation as per Regulation (EC) No. 440/2008

402 Acute Dermal Toxicity

Potassium monopersulphate, LC50 Inhalation Dusts and Mists, Rat - Male, Female

>5 mg/l for 4 hours Expert judgement Dosage caused no mortality

OECD 403 Acute Inhalation Toxicity

Carcinogenic Effects: None of the components present in this material at concentrations equal to or greater than 0.1 % are listed by IARC, NIP, OSHA or ACGIH as a Carcinogen.
Mutagenic Effects: No data found..
Teratogenic Effects: No data found.
Developmental Toxicity: No data found.

12. Ecological Information

Product name

Test

Result

Pentapotassium bis
(peroxymonosulphate) bis(sulphate)

OECD 202 Daphnia Magna sp. Acute Immobilization Test

Acute EC50 3.5 mg/l Fresh water, Daphnia Magna, 48 hours.

Pentapotassium bis
(peroxymonosulphate) bis(sulphate)

OECD 203 Fish, Oncorhynchus Mykiss Acute Toxicity Test

Acute LC50 53 mg/l Fresh water, Oncorhynchus Mykiss, 96 hours.

Dipotassium
Peroxodisulphate

Acute EC50 120 mg/l, Daphnia – Daphnia Magna, 48 hours.

Dipotassium
Peroxodisulphate

Acute LC50 76.3 mg/l, Fish – Oncorhynchus
Mykiss, 96 hours.

Dipotassium disulphate

Acute EC50 720 mg/l Readacross from CAS # 7778-80-5, Fresh water, Daphnia Magna, 48 hours.

Dipotassium disulphate

Acute LC50 680 mg/l Readacross from CAS # 7778-80-5, Fresh water, Fish – Pimephales
Promelas, 96 hours.

Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

13. Disposal Considerations

Whatever cannot be saved for recovery should be handled as hazardous waste and sent to an approved waste facility.

14. Transport Information

Land Transport DOT USA TDG Canada & ADR/RID Europe:
UN-Number: 3260 Class: 8, Packing group: II
Proper shipping name: Corrosive solids, n.o.s. (Potassium hydrogenperoxomonosulphate)
Sea Transport IMO/IMDG:
UN-Number: 3260 Class: 8, Packing group: II
Proper shipping name: Corrosive solids, n.o.s. (Potassium hydrogenperoxomonosulphate)
Air Transport ICAO/IATA:
UN-Number: 3260 Class: 8, Packing group: II
Proper shipping name: Corrosive solids, n.o.s. (Potassium hydrogenperoxomonosulphate)

15. Regulatory Information

USA:
SARA 311/312 Hazards: See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Section 16 - Additional Information

European Labeling in Accordance with EC Directives:
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H335: May cause respiratory irritation.

DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.

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American Molecules, also known as ammol.org is a distributor, supplier and manufacturers' representative of all types of Pharmaceuticals, Functional Ingredients, Excipients and Specialty Chemicals in Texas USA. Our principals manufacture supply and export USP NF BP, Ph Eur, etc grades of chemicals pure and reagent grade, mineral fortifiers, FCC food grade. Tailor made particle size and customized specifications are offered. The principal's facility is having one or more of the certifications like FDA approval and GLP, cGMP, ISO9001, ISO14001, ISO/IEC 17025, ISO22000, FSSC 22000, ISO45001, FSSAI, Kosher, HALAL, COPP, WHO-GMP certified and Written Confirmation (WC) for export to Europe is available. The manufacturers suppliers and exporters observe WHO Good Manufacturing Practices and Good Laboratory Practices.

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Suppliers and Manufacturers' Representative:
American Molecules - Ammol.org USA
9910 Bent Oak Dr
Houston, TX 77040, USA
Call Toll Free: 1-855-55-AMMOL 1-855-552-6665
Email: info@ammol.org