American Molecules - Ammol.org USA

Selenium Dioxide SDS Safety Data Sheet of Supplier Exporter Manufacturers' Representative

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Selenium Dioxide
CAS Number: 7446-08-4

Molecular Formula: SeO2
Molecular Weight: 110.96

Selenium Dioxide Suppliers
Selenium Dioxide

Selenium Dioxide SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
 04-Feb-24

Section 1. Product Information

Product Name & Other Names: Selenium Dioxide.
CAS No.: 7446-08-4
EINECS EC Number: 231-194-7
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: American Molecules, 9910 Bent Oak Dr, Houston, TX 77040, USA.
Call Toll Free: 1-855-55-AMMOL 1-855-552-6665.
In case of emergency contact: Will be given with the supply.

Section 2: Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Inhalation (Category 3), H331
Acute toxicity, Oral (Category 3), H301
Specific target organ toxicity - repeated exposure (Category 2), H373
Chronic aquatic toxicity (Category 1), H410

Labelling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Aquatic Toxicity
Aquatic Toxicity

GHS Label Elements
Health Hazard
Health Hazard

GHS Label Elements
Toxic
Toxic

Signal Words: Warning

Hazard statements:
H301 Toxic if swallowed.
H331 Toxic if inhaled.
H373 May cause damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P314: Get medical advice/attention if you feel unwell.
P330: Rinse mouth.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

Section 3: Composition and Information on Ingredients

Product Name & Other Names: Selenium Dioxide.
CAS No.: 7446-08-4
EINECS EC Number: 231-194-7

Section 4. First Aid & Procedure

Always get medical attention after the first aid is over.

Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Skin:
 Immediately flush skin with plenty of water for at least 15 minutes. Remove and wash contaminated clothing and shoes before reuse. Get medical attention if irritation develops.
Eyes:
 Immediately flush eyes with plenty of water for 15 minutes, occasionally lifting upper and lower eyelids. Hold eyelids apart during irrigation. Get medical attention.
Inhalation:
 Remove person to fresh air. If breathing is difficult, give oxygen. If not breathing administer artificial respiration. Get medical attention.

Section 5. Fire Fighting Measures

Fire/Explosion: Not considered to be a fire and explosion hazard.
Extinguishing Medium: 
Water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Fire Fighting Instructions: Use suitable protective equipment for surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.

Section 6. Spills and Disposals

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container.

Section 7. Handling and Storage

Precautions for safe handling: Avoid prolonged or repeated exposure. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents.

Section 8. Exposure Controls & Personal Protection

Exposure Limits:
OSHA PEL: 0.2 mg/COM Ceiling for Selenium compounds (as Se).
ACGIH TLV: 0.2 mg/CBM (TWA) Selenium compounds (as Se).
Engineering Controls: Use adequate exhaust ventilation to keep airborne concentrations below the allowable exposure limit.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Section 9. Physical & Chemical Data

Appearance: Solid.
Odor: Not available.
Odor threshold: Not available.
pH: No data found.
Relative density: about 3.95
Melting Point: 315C.
Initial boiling point and boiling range
: No data found.
Flash point: No data found.
Auto-ignition temperature: No data found.
Decomposition temperature: No data found.
Upper/lower flammability or explosive limits: No data found.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility: Soluble in water.
Viscosity: No data found.

Section 10. Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Incompatibility (Materials to Avoid):
 Strong reducing agents, Organic materials, Powdered metals and Moisture.
Conditions to Avoid: Incompatible materials, exposure to moist air or water, excessive heat.
Hazardous Decomposition Products: Selenium Oxide and fumes.
Hazardous Polymerization:
 Will not occur.

Section 11. Toxicological Information

Toxicity to Animals: LD50 Oral - Rat - 68.1 mg/kg.
Carcinogenicity: Not listed as a suspected/confirmed carcinogen by ACGIH, IARC, NTP, SHA.
Mutagenic: Possible for humans. Laboratory experiments have shown mutagenic effects.
Specific target organ toxicity: repeated exposure: May cause damage to organs through prolonged or repeated exposure.

Section 12. Ecological Information

Toxicity to fish: LC50 - Pimephales promelas (fathead minnow) - 2.9 mg/l - 96.0 h
Toxicity to algae: Growth inhibition EC50 - Scenedesmus acutus - 0.1 mg/l - 3 d
Growth inhibition LOEC - Pseudokirchneriella subcapitata - 24.63 mg/l - 6 d
Ecotoxicity: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Results of PBT and vPvB Assessment: No data found.
Persistence and Degradability: Soluble in water. Persistence is unlikely.
Mobility in soil: Likely to be mobile due to water solubility.
Environmental Precautions: DO NOT DISCHARGE into drains and rivers.

Section 13. Disposal Suggestions

Dispose of in accordance with all applicable local, state, and federal regulations at an approved waste disposal facility.

Section 14. Transport and Label Information

Land Transport DOT USA, TDG Canada & ADR/RID Europe:
UN-No UN3283
Proper Shipping Name SELENIUM COMPOUND, N.O.S
Proper technical name: Selenium Dioxide
Hazard Class 6.1
Packing Group III.
Sea Transport IMDG/IMO:
UN-No UN3283
Proper Shipping Name SELENIUM COMPOUND, N.O.S
Hazard Class 6.1
Packing Group III.
Air Transport IATA/ICAO:
UN-No UN3283
Proper Shipping Name SELENIUM COMPOUND, N.O.S
Hazard Class 6.1
Packing Group III.

Section 15. Regulatory Information

USA:
SARA 311/312 Hazards: See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Section 16. Other Information

European Labeling in Accordance with EC Directives:
H301 = Toxic if swallowed.
H301 + H331 = Toxic if swallowed or if inhaled.
H373 = May cause damage to organs through prolonged or repeated exposure.
H400 = Very toxic to aquatic life.

DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.

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American Molecules, also known as ammol.org is a distributor, supplier and manufacturers' representative of all types of Pharmaceuticals, Functional Ingredients, Excipients and Specialty Chemicals in Texas USA. Our principals manufacture supply and export USP NF BP, Ph Eur, etc grades of chemicals pure and reagent grade, mineral fortifiers, FCC food grade. Tailor made particle size and customized specifications are offered. The principal's facility is having one or more of the certifications like FDA approval and GLP, cGMP, ISO9001, ISO14001, ISO/IEC 17025, ISO22000, FSSC 22000, ISO45001, FSSAI, Kosher, HALAL, COPP, WHO-GMP certified and Written Confirmation (WC) for export to Europe is available. The manufacturers suppliers and exporters observe WHO Good Manufacturing Practices and Good Laboratory Practices.

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Suppliers and Manufacturers' Representative:
American Molecules - Ammol.org USA
9910 Bent Oak Dr
Houston, TX 77040, USA
Call Toll Free: 1-855-55-AMMOL 1-855-552-6665
Email: info@ammol.org