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Selenium Glycinate or Selenium Amino Acid Chelate SDS Safety Data Sheet of Supplier Exporter Manufacturers' Representative |
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Selenium Glycinate or Selenium Amino Acid Chelate
Selenium Glycinate or Selenium Amino Acid Chelate
Selenium Glycinate or Selenium Amino Acid Chelate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 19-Jan-25
1. Product Identification
Product Name & Other Names: Selenium Glycinate or Selenium Amino Acid Chelate
CAS No.: Not available
Relevant uses and uses advised against (if any): Industrial use only.
Supplier: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral Category 4, H302
Acute toxicity, dermal Category 4, H312
Acute toxicity, inhalation Category 4, H332
Hazardous to the aquatic environment, acute hazard Category 2, H401
Labeling according to Regulation (EC) No 1272/2008
GHS Label Elements  Irritant |
Signal Words: Warning
Hazard statements:
H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H332: Harmful if inhaled.
H401: Toxic to aquatic life.
Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P270 Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P314: Get Medical advice/attention if you feel unwell.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+352: IF ON SKIN: Wash with soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/ attention.
General comments on selenium chemicals:
Carcinogenic Effects: Classified 3 (Not classifiable for human.) by IARC [Sodium selenite].
Mutagenic Effects: Mutagenic for mammalian somatic cells. [Sodium selenite]. Mutagenic for bacteria and/or yeast. [Sodium selenite].
Teratogenic Effects: Classified POSSIBLE for human [Sodium selenite].
Developmental Toxicity: Classified Reproductive system/toxin/female, Reproductive system/toxin/male [POSSIBLE] [Sodium selenite].
The substance may be toxic to blood, kidneys, liver, skin, central nervous system (CNS). Repeated or prolonged exposure to the substance can produce target organs damage.
Inhalation: This material is a dust or may produce dust. May cause respiratory tract (nose, throat, airways), and mucous membrane irritation with coughing, sneezing, breathing difficulty and headache. Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing in large amounts of this material may be harmful. Prolonged or repeated inhalation of selenium dust may cause bronchitis.
Ingestion: Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. Over-ingestion of Selenium may cause gastrointestinal upset with nausea, vomiting, and diarrhea, garlic like odor of the breath and sweat, metallic taste. Over-ingestion of selenium may be harmful or fatal. While selenium in the diet is essential for proper nutrition, long-term ingestion of high amounts may cause gastrointestinal tract and nervous system disturbances (giddiness, lassitude, irritability), breathing difficulty (dyspnea), skin sores, and yellowish skin, pallor, loss of hair & nails and decayed or spotted teeth. In some individuals, nervous system effects may progress to numbness, convulsions, and paralysis. Overexposure may cause anemia, kidney damage, and liver damage. Acute selenium poisoning is potential lethal due to cardiac failure and/or pulmonary edema.
3. Composition/Information on Ingredients
Product Name & Other Names: Selenium Glycinate or Selenium Amino Acid Chelate
CAS No.: Not available
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Give large amounts of water to drink. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention.
5. Fire Fighting Measures
Fire: Not classed as flammable. Slightly flammable to flammable in presence of heat. Non-flammable in presence of shocks. Slightly explosive in presence of open flames and sparks. Non-explosive in presence of shocks.
Fire Extinguishing Media: Dry chemical, foam, or carbon dioxide. Do not use a solid stream of water. Water spray may be used to keep fire exposed containers cool.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Ensure adequate ventilation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Pick up, or shovel and place in an appropriate waste disposal container.
Large Spill: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Keep away from heat. Keep away from sources of ignition. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements, or confined areas; dike if needed. Eliminate all ignition sources. Stop leak if without risk. Sweep and shovel and place in an appropriate waste disposal container. Keep in suitable, closed containers for disposal.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing materials and acids.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: TWA: 10 (mg/m3). Consult local authorities for acceptable exposure limits.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent and engineering controls are not feasible, consult an industrial hygienist.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
Appearance: A fine, free flowing spray dried light-yellow to cream powder.
Odor: Not No information found.
Odor threshold: No information found.
pH: No information found.
Relative density: No information found.
Melting point/freezing point: No information found.
Initial boiling point and boiling range: No information found.
Flash point: No information found.
Auto-ignition temperature: No information found.
Decomposition temperature: No information found.
Upper/lower flammability or explosive limits: No information found.
Vapor pressure: No information found.
Vapor density: No information found.
Evaporation rate: No information found.
Flammability (solid, gas): No information found.
Partition coefficient: n-octanol/water: No information found.
Solubility(ies): Soluble in water.
Viscosity: No information found.
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide, carbon monoxide, nitrogen oxides, selenium oxides and fumes may form when heated to decomposition.
Hazardous Polymerization: None reported.
Incompatibilities: Acids, oxidizing agents.
Conditions to Avoid: Heat, flames, dust generation, ignition sources and incompatibles.
11. Toxicological Information
LD50 Oral – Rat: No information found.
Carcinogenic Effects: Classified 3 (Not classifiable for human.) by IARC [Sodium selenite].
Mutagenic Effects: Mutagenic for mammalian somatic cells. [Sodium selenite]. Mutagenic for bacteria and/or yeast. [Sodium selenite].
Teratogenic Effects: Classified POSSIBLE for human [Sodium selenite].
Developmental Toxicity: Classified Reproductive system/toxin/female, Reproductive system/toxin/male [POSSIBLE] [Sodium selenite].
Please see section 2.
12. Ecological Information
Results of PBT and vPvB assessment: No information found.
Environmental Fate: No information found.
Toxicity to fish LC50 - Lepomis macrochirus (Bluegill): Not available.
Environmental Toxicity: The LC50/96-hour values for fish are from 10 to over 100 mg/l. This material may be toxic to aquatic life.
Persistence and Degradability: No No information found.
Bioaccumulation/ Accumulation: No information found.
Mobility: No information found.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Follow all the pollution control rules.
14. Transport Information
DOT USA, TDG Canada & ADR/RID Europe: Not dangerous goods.
IATA/ ICAO & IMDG/IMO: Not dangerous goods.
15. Regulatory Information
USA:
SARA 311/312: See section 2.
16. Other Information
Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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