Benzylamine or Benzyl Amine or Phenylmethanamine SDS Safety Data Sheet of Supplier Exporter Manufacturers' Representative
Email: info@ammol.orgCall Toll Free +1-855-552-6665
Toll Free: 1-855-55-AMMOLBenzylamine or Benzyl Amine or Phenylmethanamine
CAS Number: 100-46-9
Molecular Formula: C7H9N or C6H5CH2NH2
Molecular Weight: 107.16
Benzylamine or Benzyl Amine or PhenylmethanamineBenzylamine or Benzyl Amine or Phenylmethanamine SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 08-Feb-261. Product Identification
Product Name & Other Names: Benzylamine or Benzyl Amine or Phenylmethanamine.
CAS No.: 100-46-9
EINECS EC Code: 202-854-1
Molecular Weight: 107.16
Molecular Formula: C7H9N or C6H5CH2NH2
Relevant uses and uses advised against (if any): Fracturing and Industrial Manufacturing Use.
Supplier: American Molecules, 9910 Bent Oak Dr, Houston, TX 77040, USA.
Call Toll Free: 1-855-55-AMMOL 1-855-552-6665.
In case of emergency contact: Will be given with the supply.2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008Combustible liquid (Category 4), H227
Acute toxicity, Oral (Category 3), H302
Acute toxicity, Dermal (Category 4), H312
Skin corrosion/irritation (Category 1A, B, C), H314Labeling according to GHS USA & Regulation (EC) No 1272/2008
GHS Label Elements
CorrosiveSignal Words: Danger
Hazard statements:
H227: Combustible liquid
H302+ H312: Harmful if swallowed or in contact with skin.
H314: Causes severe skin burns and eye damage.Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+ P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P363: Wash contaminated clothing before reuse.3. Composition/Information on Ingredients
Product Name & Other Names: Benzylamine or Benzyl Amine or Phenylmethanamine.
CAS No.: 100-46-9
EINECS EC Code: 202-854-14. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Mists and vapors can irritate the throat and respiratory tract. High vapor concentrations may cause central nervous system effects. May be fatal if inhaled. Symptoms may include headaches, dizziness, and drowsiness. Get medical attention.
Ingestion: Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea and even death. Contact the medical center quickly. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Causes corrosive burns. Brief exposures may cause irritation and defatting of the skin. Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Causes burns and may result in permanent injury to eyes including blindness. Check for and remove any contact lenses. Immediately flush your eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention.5. Fire Fighting Measures
Fire: Flash point: 65C literature.
Auto ignition temperature: 405C.
Toxic fumes, nitrogen oxides and carbon monoxide may be formed in fire. Explosive mixtures can form with air. Solvent vapors can travel to an ignition source and flash back.
Fire Extinguishing Media: Dry chemical, foam, carbon dioxide or water fog. Solid water streams may spread burning liquid.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and a suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Ensure adequate ventilation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Contain spilled material. Isolate spill or leak area immediately. Keep unauthorized personnel away. Stay upwind. Keep out of low areas where vapors may accumulate. Eliminate all ignition sources (no smoking, flares, sparks, or flames) in the immediate area. Keep away from heat. Keep away from sources of ignition. Provide ventilation. Prevent entry into waterways, sewers, basements, or confined areas. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean non-sparking tools.7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like acids, oxidizing agents, heat and sparks. Containers may be hazardous when empty.8. Exposure Controls/Personal Protection
Airborne Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent and engineering controls are not feasible, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.9. Physical and Chemical Properties
Appearance: Colorless liquid.
Odor: Weak ammonia-like odor.
Odor threshold: Not available.
pH: 11.4 for 100 g/l in water @ 20C.
Relative density: about 0.98
Melting point/freezing point: 10C literature.
Initial boiling point and boiling range: 185C literature.
Flash point: 65C literature.
Auto-ignition temperature: 405C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Miscible with water. miscible in ethanol, diethyl ether very soluble in acetone.
Viscosity: Not available.
Molecular Weight: 107.16
Molecular Formula: C7H9N or C6H5CH2NH210. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage. Forms explosive mixtures with air on intense heating.
Hazardous Decomposition Products: Carbon dioxide, carbon monoxide, nitrogen oxides and toxic fumes may form when heated to decomposition.
Hazardous Polymerization: Not reported.
Incompatibilities: Acids, oxidizing agents, heat, and sparks.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.11. Toxicological Information
Toxicity to Animals:
LD50 Oral Rat: 552 mg/kg.
LC50 Inhalation Rat: 3 h - > 0.65 mg/l.
LD50 Dermal Rabbit: 1350 mg/kg
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.12. Ecological Information
Toxicity to fish: flow-through test LC50 - Pimephales promelas (fathead minnow) - 102 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 60 mg/l - 48 h.
Persistence and Degradability: Unlikely to persist due to water solubility.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with law.
14. Transport Information
DOT USA, TDG Canada & ADR/RID Europe:
UN Number: UN2735
Hazard Class: 8
Proper Shipping Name: UN2735, Amines, liquid, corrosive, n.o.s. (Benzylamine), 8, PG II.
IMDG/IMO & IATA/ICAO:
UN Number: UN2735
Hazard Class: 8
Proper Shipping Name: UN2735, Amines, liquid, corrosive, n.o.s. (Benzylamine), 8, PG II.15. Regulatory Information
USA:
SARA 311/312 Hazards: Acute Hazard, Fire Hazard. See section 2.
California Prop 65: None of the chemicals in this product are listed.Section 16 - Additional Information
European Labeling in Accordance with EC Directives:
H227: Combustible liquid
H302+ H312: Harmful if swallowed or in contact with skin.
H314: Causes severe skin burns and eye damage.Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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American Molecules, also known as ammol.org is a distributor, supplier and manufacturers' representative of all types of Pharmaceuticals, Functional Ingredients, Excipients and Specialty Chemicals in Texas USA. Our principals manufacture supply and export USP NF BP, Ph Eur, etc grades of chemicals pure and reagent grade, mineral fortifiers, FCC food grade. Tailor made particle size and customized specifications are offered. The principal's facility is having one or more of the certifications like FDA approval and GLP, cGMP, ISO9001, ISO14001, ISO/IEC 17025, ISO22000, FSSC 22000, ISO45001, FSSAI, Kosher, HALAL, COPP, WHO-GMP certified and Written Confirmation (WC) for export to Europe is available. The manufacturers suppliers and exporters observe WHO Good Manufacturing Practices and Good Laboratory Practices.
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Suppliers and Manufacturers' Representative:
9910 Bent Oak Dr
Houston, TX 77040, USA
Call Toll Free: 1-855-55-AMMOL 1-855-552-6665
Email: info@ammol.org
8 February, 2026