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Sodium Chlorite Powder & Solution SDS Safety Data Sheet of Supplier Exporter Manufacturers' Representative |
Email: info@ammol.org |
Call Toll Free +1-855-552-6665 |
Sodium Chlorite Powder & Solution
CAS Number: 7758-19-2
Molecular Formula: NaClO2
Molecular Weight: 90.45
Sodium Chlorite Powder & Sodium Chlorite Solution
Sodium Chlorite 16% to 31% Solution SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 04-Feb-24
1. Product & Company Identification
Product/Synonyms: Sodium Chlorite or Stabilized chlorine dioxide in water
CAS No.: 7758-19-2 for dry material.
EINECS EC code number: 231-836-6
Intended Use: Oil & Gas Wells fracturing and Industrial Manufacturing.
Recommended uses and uses advised against (if any): Precursor for generation of chlorine dioxide gas used in water treatment.
Supplier: American Molecules, 9910 Bent Oak Dr, Houston, TX 77040, USA.
Call Toll Free: 1-855-55-AMMOL 1-855-552-6665.
In case of emergency contact: Will be given with the supply.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Corrosive to Metals Category 1, H290
Health, Acute toxicity, 3 Oral, H302
Health, Acute toxicity, 3 Dermal, H311
Health, Serious eye damage/eye irritation Category 1, H318
Health, Specific target organ toxicity - Single exposure, Category 2, H373
Environmental, Hazards to the aquatic environment - acute hazard, 1, H400
Labeling according to GHS USA & Regulation (EC) No 1272/2008
GHS Label Elements  Toxic |
GHS Label Elements |
GHS Label Elements |
Signal Word: Danger
Hazard Statements:
H290: May be corrosive to metals.
H302: Harmful if swallowed.
H311: Toxic in contact with skin.
H318: Causes serious eye damage.
H373: May cause damage to organs through prolonged or repeated exposure.
H400: Very toxic to aquatic life.
EUH032: Contact with acids liberates very toxic gas.
This is a dilute product. However, it must be handled carefully. It may intensify fire, oxidizer.
Precautionary Statements
P234: Keep only in original container.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P330: If swallowed, rinse mouth.
P337+P313 If eye irritation persists: Get medical advice/ attention.
3. Composition/Information on Ingredients
Ingredient:| Chemical Name & CAS Number | % Range |
Sodium Chlorite -- 7758-19-2 |
15%-31% |
Sodium Chloride - 7647-14-5 |
0%-5% |
Sodium Chlorate - 7775-09-9 |
0%-3% |
Water --------------- 7732-18-5 |
77%-98% |
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used. Wash clothing & shoes before reuse. Get medical attention.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.
5. Fire Fighting Measures
Fire: Sodium Chlorite solution is not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents. Heating will release chlorine dioxide or hydrochloric acid.
Explosion: An explosion hazard when mixed with finely powdered organic matter, metal powder or reducing agents.
Fire Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Sealed containers may rupture when heated.
Hazardous Combustible Products: If product dry, heat or friction can easily ignite this product. Do not allow this product to dry on cloth or clothing. Oxidation can cause a fire hazard. Hydrogen chloride and Chlorine dioxide will evolve.
6. Accidental Release Measures
Personal precautions, protective equipment, environmental precautions and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Do not approach facing the wind. Do not touch the spilled material. Keep away from drains, surface and groundwater and soil.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. It is an oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Do not touch spilled material. Prevent entry into sewers. Eliminate all ignition sources.
Evacuation procedures must be placed into effect. Evacuate all non-essential personnel. Hazardous concentrations in air may be found in local spill area and immediately downwind. Utilize emergency response personal protective equipment prior to the start of any response. This product may represent an explosion hazard, in the form of explosive chlorine dioxide gas if it contacts acid or chlorine. Remove all sources of ignition, such as flames, hot glowing surfaces, or electric arcs. Stop source of spill as soon as possible and notify appropriate personnel. Notify all downstream water users of possible contamination. Spill materials may be absorbed using clay, soil, or non-flammable commercial absorbents. Flush spill area with large amounts of water. If allowed to dry, dried material can ignite in contact with combustible materials so do not allow spills to dry up.
Deactivating Materials: Small spills that have been diluted with water can be neutralized with sodium sulphite or sodium bisulphite solutions.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices with proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc).
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like reducing agents, organic material and powdered metals, heat, sulfur containing compounds, acids. Isolate from heat and sun. Separate from combustibles, organic or other readily oxidizable materials. Avoid storage on wood floors.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: - Not established. Maintain Shower, Eye Wash and use under good ventilation only.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
Appearance: Clear to yellow solution.
Odor: Chlorine odor.
Odor threshold: Not available.
pH: 7 to 13.
Relative density: 1.05 to 1.23
Boiling Point: 106C
Melting Point: 0C
Flash point: No data found.
Auto-ignition temperature: No data found.
Decomposition temperature: No data found.
Upper/lower flammability or explosive limits: No data found.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility: Soluble in water.
Viscosity: No data found.
10. Stability and Reactivity
Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Decomposed by heat, sunlight, and organic substances. Burning may produce chlorine and its oxide and hydrochloric acid.
Hazardous Polymerization: Will not occur.
Incompatibilities: Reducing agents, organic material and powdered metals, heat, sulfur containing compounds, acids.
Conditions to Avoid: Heat, combustible materials and incompatibles.
11. Toxicological Information
Oral rat LD50: 165 mg/kg on 100% basis.
Carcinogenic Effects: Not listed by NTP, IARC, OSHA, or any other authority as a carcinogen.
Teratogenic Effects: No data found.
Mutagenic Effects: No data found.
Developmental Toxicity: No data found.
Reproductive Effects: No data found.
12. Ecological Information
Environmental Fate: Fish Toxicity TL50 (48 hours, Daphnia Magna): 0.29mg/L.
Persistence and Degradability: Not likely to persist due to water solubility.
Mobility: Likely to be mobile due to water solubility.
Biodegradability: Sodium chlorite in water will eventually degrade to sodium chloride. Sodium chlorite in contact with acidic soil could produce chlorine dioxide.
Environmental Toxicity: This product is toxic to fish and aquatic organisms. Do not discharge effluent containing this product into bodies of water unless in accordance with law.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility.
14. Transport Information
Land Transport DOT USA, TDG Canada & ADR/RID Europe:
Proper Shipping Name: CHLORITE SOLUTION
UN/NA: UN 1908; Hazard Class: 8; Packing Group: II.
Sea Transport IMDG/IMO:
Proper Shipping Name: CHLORITE SOLUTION
UN/NA: UN 1908; Hazard Class: 8; Packing Group: II.
Air Transport IATA/ICAO:
Proper Shipping Name: CHLORITE SOLUTION
UN/NA: UN 1908; Hazard Class: 8; Packing Group: II.
15. Regulatory Information
USA:
SARA 311/312 Hazards: See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Section 16 - Additional Information
European Labeling in Accordance with EC Directives:
H290: May be corrosive to metals.
H302: Harmful if swallowed.
H311: Toxic in contact with skin.
H318: Causes serious eye damage.
H373: May cause damage to organs through prolonged or repeated exposure.
H400: Very toxic to aquatic life.
EUH032: Contact with acids liberates very toxic gas.
DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.
Sodium Chlorite Powder 80% SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 31-Mar-2023
1. Product & Company Identification
Product/Synonyms: Sodium Chlorite Powder.
CAS No.: 7758-19-2 for main ingredient.
EINECS EC Number: 231-836-6
Intended Use: Oil & Gas Wells fracturing and Industrial Manufacturing.
Recommended uses and uses advised against (if any): Used in water treatment, laboratory and industries.
Supplier: American Molecules, 4220 Cartwright Rd, Suite 702, Missouri City, TX 77459, USA
Call Toll Free: 1-855-55-AMMOL 1-855-552-6665.
In case of emergency contact: Will be given with the supply.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Oxidizing solids Category 1, H271
Health, Acute toxicity, Category 4 Oral, H302
Health, Acute toxicity, Category 2 Dermal, H311
Skin corrosion Sub-category 1B, H314
Health, Specific target organ toxicity - Single exposure, Category 2, H373
Environmental, Hazards to the aquatic environment - acute hazard, 1, H400
Labeling according to GHS USA & Regulation (EC) No 1272/2008
GHS Label Elements Toxic |
GHS Label Elements |
GHS Label Elements |
GHS Label Elements |
GHS Label Elements |
|
Signal Word: Danger
Hazard Statements:
H271: May cause fire or explosion; strong oxidizer.
H302: Harmful if swallowed.
H310: Fatal in contact with skin.
H314: Causes severe skin burns and eye damage.
H373: May cause damage to organs through prolonged or repeated exposure.
H400: Very toxic to aquatic life.
EUH032: Contact with acids liberates very toxic gas.
Precautionary Statements
P234: Keep only in original container.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get Medical advice/attention if you feel unwell.
P330: If swallowed, rinse mouth.
P337+P313 If eye irritation persists: Get medical advice/ attention.
3. Composition/Information on Ingredients
Product/Synonyms: Sodium Chlorite Powder.
CAS No.: 7758-19-2 for main ingredient.
EINECS EC Number: 231-836-6
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used. Wash clothing & shoes before reuse. Get medical attention.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.
5. Fire Fighting Measures
Fire: Not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents. Heating will release chlorine dioxide or hydrochloric acid.
Explosion: An explosion hazard when mixed with finely powdered organic matter, metal powder or reducing agents.
Fire Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.
Hazardous Combustible Products: If product dry, heat or friction can easily ignite this product. Do not allow this product to dry on cloth or clothing. Oxidation can cause a fire hazard. Hydrogen chloride and Chlorine dioxide will evolve.
6. Accidental Release Measures
Personal precautions, protective equipment, environmental precautions and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Do not approach facing the wind. Do not touch the spilled material. Keep away from drains, surface and groundwater and soil.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. It is an oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Do not touch spilled material. Prevent entry into sewers. Eliminate all ignition sources.
Evacuation procedures must be placed into effect. Evacuate all non-essential personnel. Hazardous concentrations in air may be found in local spill area and immediately downwind. Utilize emergency response personal protective equipment prior to the start of any response. This product may represent an explosion hazard, in the form of explosive chlorine dioxide gas if it contacts acid or chlorine. Remove all sources of ignition, such as flames, hot glowing surfaces, or electric arcs. Stop source of spill as soon as possible and notify appropriate personnel. Notify all downstream water users of possible contamination. Spill materials may be covered using clay, soil, or non-flammable commercial absorbents.
Deactivating Materials: Small spills that have been diluted with water can be neutralized with sodium sulphite or sodium bisulphite solutions.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices with proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like reducing agents, organic material and powdered metals, heat, sulfur containing compounds, acids. Isolate from heat and sun. Separate from combustibles, organic or other readily oxidizable materials. Avoid storage on wood floors.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: - Not established. Maintain Shower, Eye Wash and use under good ventilation only.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
Appearance: White to off-white powder, crystals, or flakes.
Odor: Chlorine odor.
Odor threshold: Not available.
pH: No data found.
Relative density: No data found.
Boiling Point: No data found.
Melting Point: No data found.
Flash point: No data found.
Auto-ignition temperature: No data found.
Decomposition temperature: No data found.
Upper/lower flammability or explosive limits: No data found.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility: Soluble in water.
Viscosity: No data found.
10. Stability and Reactivity
Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Decomposed by heat, sunlight, and organic substances. Burning may produce chlorine and its oxide and hydrochloric acid.
Hazardous Polymerization: Will not occur.
Incompatibilities: Reducing agents, organic material and powdered metals, heat, sulfur containing compounds, acids.
Conditions to Avoid: Heat, combustible materials, and incompatibles.
11. Toxicological Information
Oral rat LD50: 165 mg/kg on 100% basis.
Carcinogenic Effects: Not listed by NTP, IARC, OSHA, or any other authority as a carcinogen.
Teratogenic Effects: No data found.
Mutagenic Effects: No data found.
Developmental Toxicity: No data found.
Reproductive Effects: No data found.
12. Ecological Information
Environmental Fate: Fish Toxicity TL50 (48 hours, Daphnia Magna): 0.29mg/L
Biodegradability: Sodium chlorite in water will eventually degrade to sodium chloride. Sodium chlorite in contact with acidic soil could produce chlorine dioxide.
Environmental Toxicity: This product is toxic to fish and aquatic organisms. Do not discharge effluent containing this product into bodies of water unless in accordance with law.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility.
14. Transport Information
Land Transport DOT USA, TDG Canada & ADR/RID Europe:
Proper Shipping Name: SODIUM CHLORITE
UN/NA: UN 1496; Hazard Class: 5.1; Packing Group: II.
Sea Transport IMDG/IMO:
Proper Shipping Name: SODIUM CHLORITE
UN/NA: UN 1496; Hazard Class: 5.1; Packing Group: II.
Air Transport IATA/ICAO:
Proper Shipping Name: SODIUM CHLORITE
UN/NA: UN 1496; Hazard Class: 5.1; Packing Group: II.
15. Regulatory Information
USA:
SARA 311/312 Hazards: See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Section 16 - Additional Information
European Labeling in Accordance with EC Directives:
H271: May cause fire or explosion; strong oxidizer.
H302: Harmful if swallowed.
H310: Fatal in contact with skin.
H314: Causes severe skin burns and eye damage.
H373: May cause damage to organs through prolonged or repeated exposure.
H400: Very toxic to aquatic life.
EUH032: Contact with acids liberates very toxic gas.
DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.
Please visit Main Page of Sodium Chlorite Powder & Solution Suppliers.
American Molecules, also known as ammol.org is a distributor, supplier and manufacturers' representative of all types of Pharmaceuticals, Functional Ingredients, Excipients and Specialty Chemicals in Texas USA. Our principals manufacture supply and export USP NF BP, Ph Eur, etc grades of chemicals pure and reagent grade, mineral fortifiers, FCC food grade. Tailor made particle size and customized specifications are offered. The principal's facility is having one or more of the certifications like FDA approval and GLP, cGMP, ISO9001, ISO14001, ISO/IEC 17025, ISO22000, FSSC 22000, ISO45001, FSSAI, Kosher, HALAL, COPP, WHO-GMP certified and Written Confirmation (WC) for export to Europe is available. The manufacturers suppliers and exporters observe WHO Good Manufacturing Practices and Good Laboratory Practices.
Suppliers and Manufacturers' Representative:
9910 Bent Oak Dr
Houston, TX 77040, USA
Call Toll Free: 1-855-55-AMMOL 1-855-552-6665
Email: info@ammol.org